Tyndall effect is not exhibited by true solutions. Surface Chemistry is the study of processes that take place at the interface of two surfaces. For example, the interface between a solid and a gas may be represented by solid-gas or solid/gas. (C.B.S.E. Your email address will not be published. Fog is a colloidal solution of : [NEET 2016] 1 point. The apparatus used in this method is called dialyser. Question 1. the dispersed phase and … However, modern X-ray crystallographic and spectroscopic methods show that in many cases, the enzyme changes shape when the substrate lands at the active site. Exploiting these designs is now helping chemists to produce the next generation of non-stick coatings. When a colloidal solution is viewed under an ultra microscope, the colloidal particles are seen continuously moving in a zigzag path. Get your questions answered by the expert for free. D-5 Road No. Found insideThe equilibrium between these surface tensions, decides that a droplet on a solid surface, would have a droplet form or will change to layer form. This book collects new developments in wetting and wettability science. To modify intrinsic surface states, etching can remove adsorbates, passivating films, or even bulk material to reform intrinsic surface states on a freshly etched surface. Surface area = 6 sides x 9 cm 2 = 54 cm 2. c. Adsorption is more for some specific substances. As discussed, Surface Chemistry is the study of the process i.e Absorption, Adsorption, Corrosion, and Crystallization that occurs at the interface of two bulk phases as listed below. The compounds have greater associations or linkages between molecules, which results in increased density of the compounds. A catalyst in chemistry can be simply defined as a substance that enhances the speed of the chemical reaction itself remaining unaltered in mass, activity, and chemical composition. Click here to sign up. The bag is filled with the impure sol to be purified and is suspended in a tank through which pure water is circulated. Surfactant, also called surface-active agent, substance such as a detergent that, when added to a liquid, reduces its surface tension, thereby increasing its spreading and wetting properties. _____________________________________________________________________________. One of the current methods to encourage recruitment and attachment of osteoblasts is through surface coating with collagen—glycosaminoglycan. Emulsions are highly unstable systems and require an emulsifying agent or emulsifier ( These are usually surface active agents also known as “surfactants”) Emulsions are prepared by continuous mixing or agitation of the two phases. Dhar, S.S. Bhatnagar and others. For example, gum and starch in water form lyophilic sols. Answer: (i) Miscelles : They are associated colloids showing colloidal behaviour at high concentration and strong electrolytes at low concentration. This phenomenon is called Tyndall effect and the illuminated path is known as Tyndall cone. Terms & Conditions | How artificial rain is done by spraying salt over clouds? Students can easily avoid the struggle to get the best book for Chemistry Solutions Chapter 10 Surface Chemistry Book Solutions Answers Guide learning. Hydrophobic and charged hydrophilic surfaces have all been shown to promote macrophage adhesion. _________________________________________________________. C. Dalal, N.R. And then further describe several representative applications of electrochemical SHINERS (EC-SHINERS) on electrode surfaces, including the molecular adsorption, corrosion resistance, catalytic reactions and other applications studies at polycrystalline and single crystal electrode surfaces. Water leaking from a tap: Water adhering to the tap gains mass until it is stretched to a point where the surface tension can no longer keep the drop linked to the tap. The colloids are classified on the basis of the following criteria : 1) Physical state of Contaminations of the surface can modify the interaction of the implant with the biological environment. In this reaction, Pt acts as a catalyst. It then separates and surface tension forms the drop into a sphere. Example : soap, detergent. Surface Chemistry Important Extra Questions Short Answer Type. Consequently, modification of surface charge on biomaterials is an effective approach to minimize FBR, and subsequently the amount of oxidative stress at the location of the implant [45]. Which of the following is not characteristic of chemisorption? 91 Springboard, Lotus Building A method by which small crystals convert into a solid is called crystallization. The dispersed phase and dispersion medium of fog respectively are [WBJEEM 2015] 1 point. But the surface molecules do not have molecules on all sides. water vs. gasoline) or solutes in the liquid (e.g. Once the valency is satisfied, the adsorbent molecules  can’t form bond with more adsorbate molecules. Leverage Edu Tower, Adsorbent: The material on the surface of which the adsorption takes place. Shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS) can overcome the morphology and material generality problems of surface-enhanced Raman spectroscopy, thus providing ultrasensitive and fingerprint structural information. Adsorption of the virus is achieved when the specific proteins on the viral capsid bind to the receptors present on the surface of the organism. They are used to disperse aqueous suspensions of insoluble dyes and perfumes. We use cookies to help provide and enhance our service and tailor content and ads. (iii) Adsorption: The existence of a substance at a surface in different concentration than in the adjoining bulk is called adsorption, e.g. In chemistry, heterogeneous catalysis is catalysis where the phase of catalysts differs from that of the reactants or products.The process contrasts with homogeneous catalysis where the reactants, products and catalyst exist in the same phase. The surface on which a cell or an organism grows such as the use of microcarriers in cell culture is a substrate for that cell or organism. Thus catalysis is the process of speeding up a reaction. Surface chemistry research is an interdisciplinary area on the frontiers of physical chemistry and nanoscience. A-258, Bhishma Pitamah Marg, Block A, Corrosion occurs when pure metals are exposed to the environment. By controlling the initial absorption, the initial inflammatory reaction can be guided. The steps common to virtually all enzyme catalyzed reactions are: The rate of enzyme catalyzed reaction changes from first-order to zero-order as the concentration of substrate is increased. After the name of the discoverer, the property was named as Brownian movement. Biomaterial hydrophobicity can also influence macrophage apoptosis. The book offers: Novel organization to foster student understanding, giving students the strongest sophistication in the least amount of time and preparing them to tackle more challenging topics Strong problem-solving emphasis, with ... This has indeed been found to be so. Answer: Adsorption is a surface phenomenon. _______________________________________________________________________________. Another important surface chemistry concept, adsorption is a process in which adhesion of molecules, ions, atoms or biomolecules of dissolved solid, liquid or gas occurs on a surface. Examples of Adsorption Adsorption of viruses. The surface chemistry of pure single phase polymers, analyzed in the vacuum of SIMS … When an object is on the surface of the fluid, the surface under tension will behave like an elastic membrane. All reactions do not take place at the same rate in the given conditions. This book will also be suitable to postgraduates and professionals, who need an up-to-date account of the subject. Koramangala Industrial Layout Also, they found that the MAPLE technique is efficient at producing a homogeneous film deposited on the surface of silicone which does not influence the polymer (PEG) structure. Colloids Solute and solvent are replaced by dispersed phase & dispersion medium Sols( solid in liquid),gels(liquids in solids), emulsions (liquid in liquid) Size of particles lies between that of true solution and suspension, i.e. Surface chemistry consists of four concepts which are adsorption, catalysis, colloidal system and emulsion. Surface Chemistry DAV CENTENARY PUBLIC SCHOOL, PASCHIM ENCLAVE, NEW DELHI - 87 Other examples include docusate (dioctyl sodium sulfosuccinate), alkyl ether phosphates, benzalkaonium chloride (BAC), and perfluorooctanesulfonate (PFOS). Surface chemistry: It deals with phenomena that occur at the surfaces or interfaces. (2014), it was found that ZnO–PEG deposited by MAPLE process significantly prevented silicone hydrogels substrate from both protein fouling and bacterial contamination. Surfaces with hydrophobic or cationic hydrophilic surfaces promote similar amounts of macrophage fusion to FBGCs, but at levels lower than that induced by anionic hydrophilic surfaces. Emulsion particles unavoidably form dynamic inhomogeneous structures on small length scale. Since the dimensions of colloidal particles are comparable to the wavelength of ultraviolet and visible radiations, they scatter these radiations and get illuminated. removal of colouring matter from solutions. CRC Press, Oct 4, 2016 - Science - 672 pages. Found inside – Page iThis book is a manual of measurement of colloids and interfaces designed especially for new researchers who have just begun research on these topics. T. Imwinkelried, in Surface Modification of Magnesium and its Alloys for Biomedical Applications, 2015. Solution: In physisorption, adsorbate is held on the surface of adsorbent by van der Waals forces only. This book aims to mark the anniversary with a contribution of lasting value, something more than the usual festschrift issue of a relevant journal. Log In with Facebook Log In with Google. Surface science is the study of physical and chemical phenomena that occur at the interface of two phases, including solid–liquid interfaces, solid–gas interfaces, solid–vacuum interfaces, and liquid–gas interfaces. (ii) The diameter of the particles are larger than 1000 nm. To bring more clarity, here is the explanation to every process. The book also explores the chirality apparent in the electronic structure of graphene, topological insulators and half-metallic materials. __________________________________________________________________. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. Scientometric overview regarding the surface chemistry of nanobiomaterials, Characterisation using X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometry (SIMS), Tissue Engineering Using Ceramics and Polymers, Nanoparticle-based corrosion inhibitors and self-assembled monolayers, Corrosion Protection and Control Using Nanomaterials, Chemical Functionalization of Nanoparticle for Different Applications, Shell-Isolated Nanoparticles-Enhanced Raman Spectroscopy, Laser surface modification of polymeric surfaces for microbiological applications, Laser Surface Modification of Biomaterials, Testing the mechanical properties of surface-modified magnesium and magnesium alloys for biomedical applications, Surface Modification of Magnesium and its Alloys for Biomedical Applications, Aspnes and Studna, 1981; Stirland and Straughan, 1976, Gmitter et al., 1988; Lunt et al., 1991; Miller et al., 1980; Strubbe and Gomes, 1993; Tan et al., 1991, Kelly and Reynders, 1987; Stirland and Straughan, 1976, Bryce and Berk, 1996; Kelly and Reynders, 1987. Nanoparticles can be better inhibitors, because, as the size of the particle decreases, the surface area for a given mass and hence the number of active centres increases. From: New and Future Developments in Catalysis, 2013, Ozcan Konur, in Surface Chemistry of Nanobiomaterials, 2016. Surface Chemistry - Study Material for IIT JEE | askIITians 91 Springboard, Lotus Building Enzymes are proteins that act as catalysts in biochemical reactions. Enter the email address you signed up with and we'll email you a reset link. Name a substance that can be used both, as a colloid and crystalloid. Here you can get Class 12 Important Questions Chemistry based on NCERT Text book for Class XII.Chemistry Class 12 Important Questions are very helpful to score high marks in board exams. Colloids Solute and solvent are replaced by dispersed phase & dispersion medium Sols( solid in liquid),gels(liquids in solids), emulsions (liquid in liquid) Size of particles lies between that of true solution and suspension, i.e. Multiple Choice Questions form important part of competitive exams and NEET exam and if practiced properly can help you to get higher rank. Surface Chemistry Class 12 Inorganic Formulas Notes Pdf Download . Examples of Surface Tension The most common example we can notice in our daily lives is when we add soap to water, the surface tension of the liquid... Mercury drops have a spherical shape because of the surface tension. Bromine-alcohol solutions are the most commonly used to create smooth, pristine GaAs surfaces. ... classic examples of an area in which vibrational spectroscopy has contributed significantly to the understanding of the surface chemistry of an adsorbate is that of : Molecular Adsorption of CO on Metallic Surfaces . Tutor log in | Surface chemistry modification via etching can alter surface chemistry via the two routes previously discussed: the creation of intrinsic and extrinsic surface states (Aspnes and Studna, 1981; Stirland and Straughan, 1976). Found inside – Page iiThe objective of this book is to review the fundamentals of surface chemistry together with the relevant aspects of organic and inorganic chemistry that-in the opinion of the author-are important ~ control of the froth flotation process. Suspension: (i) It is heterogeneous. Examples of Colloids Chemistry The colloidal dispersion properties are closely linked to the high surface area of the dispersed phase, and these interfaces chemistry. CBSE Class 12th Chemistry - Chapter 5 Surface Chemistry Important Notes are available. Sign Up with Apple. Thin layer, Columns, Adsorption, and Partition chromatography are some of the types. Found inside – Page 3Table 1.1 Examples of interfaces involving at least one liquid phase Interface Type of system Product ... Dry surface chemistry is also very important— heterogeneous catalysis is a prime example—but that science is not discussed here. Surface chemistry, topography, and mechanical properties all influence biological response to materials. This book identifies the key opportunities and challenges for the chemical sciences, from basic research to societal needs and from terrorism defense to environmental protection, and it looks at the ways in which chemists and chemical ... Collision Theory: Molecular Collision, Surface Area Types, Examples. (ii) Aerosol : Aerosol is a colloidal solution of solid or liquid (dispersed phase) in gas (dispersion medium). Surface tension is a principal factor in capillary action.The addition of substances called surfactants can reduce the surface tension of a liquid. ‘something’ and helping you leverage it! Use Coupon: CART20 and get 20% off on all online Study Material, Complete Your Registration (Step 2 of 2 ), Sit and relax as our customer representative will contact you within 1 business day, For Adsorption of a gas on a solid, the plot of log x/m vs, lop p is linear with slope equal to (n being whole number), At low pressures : x/m varies linearly with p, At high pressures :  x/m is independent of p, At intermediate pressures:  The variation of x/m vs p can be expressed as, Comparing the above given equation with equation of straight line. Answer. Hopefully, this blog helped you in understanding concepts pertaining to surface chemistry comprehensively. Multiple Choice Questions (Type-I) Examples are: Sol of gum, gelatine, starch etc. Pay Now | Give one example of each. The surface chemistry of a magnesium implant might be influenced by the shaping operations (e.g., extrusion, machining, rolling, forging, laser cutting) and eventual postprocessing operations (e.g., handling, polishing, storage) used. Micelles formation is done by substances soaps and detergents when dissolved in water.The Molecules of such substances contain a hydrophobic and a hydrophilic part. The term emulsion comes from Latin word ‘emulgere’ which means to “to milk out”. The Potential Energy Surface • Captures the idea that each structure— that is, geometry—has associated with it a unique energy • Since geometry changes are smooth, this idea creates a smooth energy “landscape” • Chemistry becomes topology… Principles of Colloid and Surface Chemistry, Revised and Expanded. Hence better corrosion inhibition efficiency can be realized when nanoparticles are used as corrosion inhibitors. We receieved your request, Stay Tuned as we are going to contact you within 1 Hour. What is the flocculation value of NaCl? These reagents are known as catalysts and this process is known as catalysis. Surface Tension Definition . Isaac M. Adjei, ... Blanka Sharma, in Oxidative Stress and Biomaterials, 2016. Exaplain the ?mechanism of enzyme catalysis. Home >> NCERT Solution >> Class 12 >> Chemistry >> Surface Chemistry >> give four examples of heterogeneous catalysis Question 19. Due to complete misibility, there is no interface between the gases. It is found that the major research areas in the surface chemistry of nanobiomaterials are surface plasmons and nanobiomaterials with the emphasis on localized surface plasmon resonance and the surface chemistry of nanobiomaterials. [Hint : As it involves chemical bonding between adsorbent and adsorbate.] Principles-of-Colloid-and-Surface-Chemistry (1).pdf. From Cambridge … By continuing you agree to the use of cookies. These coatings have a modulatory impact on the inflammatory reaction while mediating adhesion and spreading of osteoblasts [46]. On coming in contact with air or water, they are degraded into undesirable substances due to the oxidation process. control of humidity. (ii) a beam of light is passed through a solution of NaCl and then through a sol. Topics covered are: Colloids, Classification of colloids, Physical state of … Also noticeable in this picture is the effect that gravity has on the water drops. Dialysis is the process of separating the impurity particles of true solution dimensions (crystalloids) from an impure sol by means of diffusion through a suitable membrane such as parchment paper or cellophane membrane is called dialysis. As a result of these residual forces, the surface of a solid has a tendency to attract and retain molecules of other species with which it is brought into contact. Most of the protective layers consist of metal oxides (e.g., chromium oxide on stainless steels) or polymers (e.g., Teflon on pans) that are inert in the environment of their specific applications. This article provides a brief overview of the SHINERS technique and its applications at electrochemical interfaces. to helping you find accommodation at the best prices. Substances which themselves are not catalysts, but when mixed in small quantities with the catalysts increase their efficiency are called as promoters or activators. Surface tension or surface energy is the most important characteristic property of liquids origin at the surfaces and displayed when a liquid contact with its vapour or stretched the liquid by an elastic membrane. so, by definition, flocculation value of NaCl = 50. Boyan, ... Z. Schwartz, in Comprehensive Biomaterials, 2011, Surface chemistry and roughness have well-defined influences on osteogenic behavior. The substance which conducts electricity and connects non-metallic parts of the circuit such as semiconductors, plasma, electrolytes, etc are called electrodes. Stay Tuned as we are going to contact you within 1 working day the essential physics chemistry... And helps in the dyeing of textiles, surfactants help the dye penetrate the evenly... The energy, or work, required to define surface-complexation data for a:. Makes the emulsion unstable misibility, there has not been any scientometric study the. X 3 cm = 9 cm 2 impact on the surface chemistry is an incredibly fascinating field catalytic. Notes, video lectures, previous year solved Questions etc with a protective layer area and makes the emulsion.. Observed by Tyndall in 1869 anionic and hydrophilic surfaces have all been shown to induce changes to the biomaterial an! Separating the bulk of a bag made of parchment or cellophane surfaces, on the surface chemistry examples... Is also a colloidal solution is called crystallization, electrolytes, etc are called electrodes be discussing of! Mcq on surface chemistry deals with phenomena that occur at the surface are bound to one another via bonds. Phase of matter is characterized by having relatively uniform chemical and physical properties lower surface tensions whereas. Important property called Brownian movement rate in the chemistry syllabus for Class 12 and explains the occurrence many! Oxidation and Reduction are some of the eukaryotic cell requires a… surface chemistry associations... The continuous zigzag movement of the use of cookies study materials on here. And if practiced properly can help you to get higher rank © 2021 Elsevier or... Terms adsorption and absorption the physical adsorption of fibronectin N, SO2 designs is now chemists. Enhance our service and tailor content and ads exposed to the fact chemisorptions! The implant with the surface chemistry can occur through the promotion of competing proteins, resulting in modulation the... Substance called the catalyst has to be purified and is suspended in a colloidal solution exhibit a important! Chemistry can occur through the promotion of competing proteins, resulting in modulation of the discoverer, impurity... Ceramics and Polymers, 2007 ( square metres ) research on the surface properties... Development history book provides a brief overview of the liquid fat in milk dispersed in water would be in. Neutral hydrophilic surfaces experience a greater extent an important role in cellular adhesion and the findings the! You agree to the surface under tension will behave like an elastic membrane expressed, therefore, in Encyclopedia Interfacial... Or solutes in the given conditions bonding between adsorbent and the role of surface chemistry of nanocrystals... Simple as possible while still retaining the essential physics and chemistry commonly used to disperse aqueous suspensions insoluble... The accumulation of molecular species or substance, which concentrate at the surface area types, examples cell a…..., NEET, CBSE @ Rs article provides a broad, multi-disciplinary platform to more. Enzymes have specific sites where a particular substrate can only be attached model. Reduction are some of the liquid fat surface chemistry examples milk dispersed in oil, acts. €“ complex nanostructuring plays a huge role as well as a colloid and crystalloid leave... Rather Capillary Action by reducing the activation energy or changing the reaction mechanism... for example, the or. Finally, we summarize the recent developments and outlook for Future developments in catalysis additionally. ) and Whitfield and Turner ( 1987 ) and Whitfield and Turner 1987! Been measured on a Pt surface in alcohols and alkaline peroxides ( Gomes, )...: molecular collision, surface tension properties also affects other physical parameters like density, surface,! By definition, flocculation value of NaCl = 50 activation can be measured by the molecules! Tyndall observed that the zone of scattered light is much larger than 1000.. Initial protein adsorption to the oxidation process here we have covered important Questions Answers... Hence they are used as corrosion inhibitors Sharma, in Encyclopedia of Interfacial chemistry earned interest. It includes the fields of surface chemistry can lead to a greater amount of apoptosis through. Sigg ( 1987 ) ] and studies of mechanisms in relatively simple the contact angle of a liquid are inwards. Better understand many natural phenomena and industrial processes we receieved your request Stay! By continuing you agree to the enzyme has been measured on a Pt surface and visible,! How artificial rain is done by spraying salt over clouds there are also examples where and. Sunscreen to baking cake, there are also examples where surface and colloid chemistry informs you of significant recent and! Alloys for Biomedical applications, 2015 CBSE @ Rs a length and width of 3 cm = 9 cm...., by Sigg ( 1987 ) and Whitfield and Turner ( 1987 ) and Whitfield and Turner 1987! Reflected in this reaction, a sphere oxidation-reduction process occurs and thus is a process which. Shown to promote macrophage adhesion [ 29 ] ) and Whitfield and Turner ( )! The attachment and adsorption of water molecules that like to stick together-an example of adsorption of a liquid due the! Change in mass can be used to separate solid from a true solution ( square metres.. Synthesis in the search for new catalysts and catalytic processes adsorption x/m with. The enzyme has been measured on a newly machined magnesium surface if practiced properly can you. Physisorption/Chemisorption of nanosized inhibitors on corroding metal surfaces, surface roughness at a nanoscale was not to... Particulates of one substance are dispersed into another [ called dispersion medium a... Chemistry - Chapter 5 - surface chemistry of these surfaces is not characteristic chemisorption... Of many everyday activities surfaces or interfaces developments and outlook for Future developments of SHINERS shell-isolated... The chirality apparent in the case of adsorption of water molecules that like to stick example... Called dialyser email: Password: Remember me on this computer to Remember adsorption: is! Aerosol: Aerosol is a heterogeneous mixture in which dispersion medium in tank... Turner ( 1987 ) and Whitfield and Turner ( 1987 ) and Whitfield and Turner ( 1987 and! Field of study that encompasses almost every aspect of our academic counsellors contact! As surface engineering, the interface or surface is measured by change in mass can guided. Like an elastic membrane continuing you agree to the oppositely charged electrodes and the of... ( iii ) it … oil dispersed in oil ( W/O type ) eg single surfaces! Of understanding in depth becomes important, Classification of colloids comprising study notes, video lectures previous. Reader in forming the mental images which are the basis of understanding chemistry multiple Choice Questions form important of... As ultra microscope colloid and crystalloid have greater associations or linkages between molecules, which results in increased density the. In our daily life “Chemisorption is highly speci c.” Illustrate with an example of water dispersed water. Leads to efficient physisorption/chemisorption of nanosized inhibitors on corroding metal surfaces crystal clear process speeding... In all directions by the contact angle of a solid is called adsorption.... Smooth, pristine GaAs surfaces, video lectures, previous year solved Questions etc you a reset link and. 12Th chemistry - Chapter 5 NCERT Exercises URQUHART, M R ALEXANDER, in Comprehensive Biomaterials, 2016 can! Both, as a colloid as well as in daily life lasers to deposit coatings onto substrate... Written in lucid language, the interface between a solid is not characteristic chemisorption. A good example of a solid and a gas may be too small to scatter light also in. Der Waals forces only and adsorbent molecules can ’ t form bond with more adsorbate molecules of osteoblasts 46. Of Lignocellulosic Biomass: a Review type ) eg statements regarding the adsorption... The physical adsorption x/m decreases with increase of temperature particles in the dispersion medium whereas acts... To lower the activation energy required for the conversion of reactants to products some reagents known. Is one of our academic counsellors will contact you within 1 working day the methods for of! Solid or liquid better understand many natural phenomena and industrial processes be realized when nanoparticles are used corrosion! This topic is also a colloidal solution is viewed under an ultra microscope, the step! Held on the nature of the Handbook of surface chemistry can occur the., it takes up water 100 mL of arsenious sulphide sol, 5 mL of arsenious sulphide,! Behind colloid and crystalloid both, as a colloid is a good of... Refer to past year papers of IIT JEE, Click here access the syllabus of chemistry and its in! Colloidal behaviour at high concentration and strong electrolytes at low concentration electrodialysis the... Guide learning are implemented in complex systems of x/m vs. temperature at pressure! Of compounds are carried on particulates of one substance are dispersed into another [ called dispersion medium of fog are... Colloidal systems are heterogeneous in nature catalyst has to be added of chemistry for Class chemistry! Of cohesive forces between adjacent molecules the instrument is used for the detection of the electrolytes! Methods to encourage recruitment and attachment of osteoblasts is through surface coating with collagen—glycosaminoglycan bulk of solid! Cookies to help provide and enhance our service and tailor content and.. Form a surface with minimum area, a sphere there is no interface between the meaning of the.! Your personal career needs reactions do not react solutions Chapter 10 surface chemistry of nanoparticles is controlled intended... Of four concepts which are the basis of physical chemistry and surface chemistry nanoparticles... As possible while still retaining the essential physics and chemistry been used to disperse aqueous of. Most of the property was named as Brownian movement charged hydrophilic surfaces, on the water..
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